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Veröffentlicht am 1. Januar 2003

AMP - BWG-5 : Mont Terri Project - Geochemistry of Water in the Opalinus Clay Formation at the Mont Terri Rock Laboratory

This report presents the integrated geochemical investigations conducted at the Mont Terri Rock Laboratory (Canton Jura, Switzerland), focusing on the Opalinus Clay formation of Middle Jurassic age.

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BWG-5 : Mont Terri Project - Geochemistry of Water in the Opalinus Clay Formation at the Mont Terri Rock Laboratory
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Abstract

Berichte des BWG - Serie Geologie - BWG5
This report presents the integrated geochemical investigations conducted at the Mont Terri Rock Laboratory (Canton Jura, Switzerland), focusing on the Opalinus Clay formation of Middle Jurassic age. The main objective was to develop and evaluate methodologies for determining in situ pore water compositions in low-permeability claystones. Several sampling and analytical techniques were applied, including sealed borehole installations, high-pressure squeezing of preserved drillcores, and aqueous leaching experiments.

Complementary analyses of solutes, stable isotopes and gases were performed, yielding a comprehensive dataset on pore water chemistry. The results were assessed through geochemical modelling, enabling interpretation of the most probable in situ chemical conditions and their long-term evolution. The study highlights the crucial role of water–rock interactions, ion exchange and diffusion-controlled transport in shaping the geochemical environment of Opalinus Clay. Findings also underline the sensitivity of measurements to perturbations, especially oxidation, and stress the importance of minimising such artefacts. Overall, the project improves understanding of chemical and transport processes in claystone systems, with implications for hydrogeology, natural geochemical evolution, and potential safety assessments for underground waste disposal.

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